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In general, a key is a set of one or more columns in the table that have certain properties A compound key or composite key is a key that includes more than one column For example, you might use the combination of FirstName and LastName to look up customers A superkey is a set of one or more columns in a table for which no two rows can have the exact same values For example, in the Competitors table shown in Figure 3-1, the Name, Address, and Event columns together form a superkey because no two rows have exactly the same Name, Address, and Event values Because superkeys de ne elds that must be unique within a table, they are sometimes called unique keys Because no two rows in the table have the same values for a superkey, a superkey can uniquely identify a particular row in the table.

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Thus, all of the diagonal elements are e The o -diagonal elements are if the two atoms involved are bonded and zero if they are not It is usual to divide each row of the determinant by This corresponds to a change of energy units and leaves either 1's or 0's in the o -diagonal positions which encode the connectivity of the molecule The diagonal elements become e a , which is usually represented by x While the determinant was expanded in 3 to yield the secular equation, it is more convenient in general to diagonalize the determinant using a computer An interactive computer program, SHMO, has been written to accompany this book [102] The SHMO calculation on ethylene yields the results shown in Figure 51a The p and p orbitals are precisely one unit above and below The SHMO results are presented in Figure 5.

In other words, a program could use a superkey to nd any particular record A candidate key is a minimal superkey That means if you remove any of the columns from the superkey, it won t be a superkey anymore For example, you already know that Name/Address/Event is a superkey for the Competitors table If you remove Event from the superkey, Name/Address is not a superkey because everyone in the table is participating in multiple events so they have more than one record with the same name and address If you remove Name, Address/Event is not a superkey because Dean Daring and his roommate George Foreman share the same address and are both signed up for Pyramid Luge (They also have the same blood type They became friends and decided to become roommates when Dean donated blood for George after a particularly amboyant skateboarding accident.

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Listing 24-1 reads in an audio file, and then writes out the same sound played backwards. Note that this could also be accomplished by one call to audioop.reverse (see Handling Raw Audio Data, later in this chapter). This example does things the long way for purposes of exposition.

) Finally if you remove Address, Name/Event is still a superkey That means Name/Address/Event is not a candidate key because it is not minimal However, Name/Event is a candidate key because no two rows have the same Name/Event values and you can easily see neither Name nor Event is a superkey, so the pair is minimal You could still have a problem if one of George s other brothers, who are all named George, moves in If they compete in the same event, you won t be able to tell them apart Perhaps we should add a CompetitorId column to the table after all Note that there may be more than one superkey or candidate key in a table In Figure 3-1, Event/NextOfKin also forms a candidate key because no two rows have the same Event and NextOfKin values.

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